UDC

537.311

Authors

Koposov Gennadiy Dmitrievich
Institute of Natural Sciences and Technology, Northern (Arctic) Federal University named after M.V. Lomonosov (Arkhangelsk, Russia)
е-mail: fc.genphys@pomorsu.ru
Volkov Aleksandr Sergeevich
Institute of Natural Sciences and Technology, Northern (Arctic) Federal University named after M.V. Lomonosov (Arkhangelsk, Russia)
е-mail: a.s.volkov@narfu.ru
Tyagunin Anatoliy Vyacheslavovich
Institute of Natural Sciences and Technology, Northern (Arctic) Federal University named after M.V. Lomonosov (Arkhangelsk, Russia)
е-mail: alastor15@yandex.ru

Abstract

A new model to explain the observed deviations of frequency dependencies from the Debye formulas for the relaxational polarization and hopping conductivity is proposed. The essence of the model is based on the acceptance of Debye formulas for permittivity and conductivity and dependence of relaxation rate on electric field frequency. On the basis of the model as an example, the analysis of electrophysical properties of frozen, moisture-containing dispersing medium based on quartz powder with fructose admixture is given. Research of electrophysical properties were carried out with the help of LCR meter E7-20 in the frequency range from 25 Hz to 1 MHz, the range of temperatures was 120- 270 K, the range of concentrations of fructose admixtures was from 10^–6M to 10^–2M. The frequency dependences of electrolytic conductivity, described by exponential function of a type σ(ω) ~ ωα are constructed. Frequency dependences of relaxation rates of conductivity and permittivity have the following form: τ ~ τ₀w^−β . Parameters of exponential functions depend on the sample temperature and admixture concentration. Relaxation rate, in accordance with the principle of independence of relaxational processes, includes relaxation rate at phonon scattering mechanism and relaxation rate due to scattering by static defects. As follows from the research, frequency of external electric field influences on a scattering mechanism and consequently on the value of relaxation rate. At introduction admixture into the ice structure the determination of relaxation rate at static defects is with difficulty. It depends on disfunction of scattering mechanism, since the impurity molecule penetrating into a crystal ice structure, delays the movement of carriers.

Keywords

doped ice, electrical conductance, permittivity, relaxation rate, disperse systems

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